Products
2-(Methylthio)benzaldehyde
Another name：2-(Methylmercapto)-benzaldehyde; o-(Methylthio)benzaldehyde; 2-Methylsulfanylbenzaldehyde; 2-(methylthio) Benza;
CasNo: 7022-45-9 Purity： ≥97.0% Molecular Structure： C8H8OS
2-(METHYLTHIO) BENZALDEHYDE Basic Product Information
| Product Name | 2-(METHYLTHIO) BENZALDEHYDE | CAS | 7022-45-9 |
| Synonyms | Benzaldehyde,o-(methylthio)- (7CI,8CI);2-(Methylthio)benzaldehyde;2-Formylthioanisole;2-Methylsulfanylbenzaldehyde;NSC 144623;o-(Methylthio)benzaldehyde; | Molecular Formula | C8H8OS |
| EINECS Number | / | Molecular Structure | |
| Appearance | Yellow liquid |
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| Purity | ≥97.0% | ||
| Supply Ability | 100kg Per Month | ||
2-(METHYLTHIO) BENZALDEHYDE Appearance/Package/Shipping/Storage
Package
20kg/drum
Storage condition
Keep container tightly closed in a dry, well-ventilated place and stored in inert gas.
2-(METHYLTHIO) BENZALDEHYDE Application
Used as research compounds and pharmaceutical intermediates, it can also serve as a raw material for the development of liquid crystal material intermediates and pesticide intermediates.
2-(METHYLTHIO) BENZALDEHYDE literature
Rhodium(III)-Catalyzed Aldehyde C?H Activation and Functionalization with Dioxazolones: An Entry to Imide Synthesis
Bellière-Baca, Virginie,Clavier, Hervé,Hérault, Damien,Massouh, Joe,Petrelli, Antoine
supporting information, (2022/01/06)
A rhodium(III)-based catalytic system has been used to develop a C?H bond activation of benzaldehyde derivatives and subsequent functionalization with dioxazolones in order to afford imides. The importance of the nature of the directing group to perform selectively the aldehydic C?H bond activation has been highlighted. The scope investigation showed that this transformation could be applied to various dioxazolones and many benzaldehyde derivatives as well as an acrolein derivative. Derivatization reactions of the imide products demonstrated the synthetic utility of this rhodium-catalyzed aldehydic C?H amidation.
Nickel-Catalyzed Inter- and Intramolecular Aryl Thioether Metathesis by Reversible Arylation
Delcaillau, Tristan,Bismuto, Alessandro,Lian, Zhong,Morandi, Bill
supporting information, p. 2110 - 2114 (2019/12/24)
A nickel-catalyzed aryl thioether metathesis has been developed to access high-value thioethers. 1,2-Bis(dicyclohexylphosphino)ethane (dcype) is essential to promote this highly functional-group-tolerant reaction. Furthermore, synthetically challenging macrocycles could be obtained in good yield in an unusual example of ring-closing metathesis that does not involve alkene bonds. In-depth organometallic studies support a reversible Ni0/NiII pathway to product formation. Overall, this work not only provides a more sustainable alternative to previous catalytic systems based on Pd, but also presents new applications and mechanistic information that are highly relevant to the further development and application of unusual single-bond metathesis reactions.
Unexpected formation of 4,7-dihalobenzo[b]thiophenes using Ohira-Bestmann reagent and reactivity of the halogen-substituted benzo[b]thiophenes in Suzuki-Miyaura coupling with phenylboronic acid
Toyota, Kozo,Mutoh, Hirotaka,Kishi, Hiroki,Mikami, Shinichi,Tanaka, Hiroki,Yoshida, Shuhei,Naganuma, Daisuke
, p. 1355 - 1374 (2019/12/23)
Reaction of 2-(1-adamantylsulfanyl)-3,6-dihalobenzaldehydes with Ohira-Bestmann reagent gave 4,7-dihalobenzo[b]thiophenes along with normal alkyne products. Nine types of 4,7-dihalobenzo[b]thiophenes bearing chlorine, bromine, or iodine atoms, were prepared by this method. Regioselectivity in Suzuki-Miyaura cross coupling reactions of the 4,7-dihalobenzo[b]thiophenes with PhB(OH)2 was also studied.
Construction of highly functionalized thiophene and benzo[b]thiophene derivatives via a sequence of propargyl–allenyl isomerization/cyclization/demethylation
Chen, Dianpeng,Xing, Gangdong,Chen, Xueyuan,Yao, Jinzhong,Zhou, Hongwei
supporting information, p. 5124 - 5126 (2016/11/09)
An efficient one-pot protocol for the synthesis of functionalized thiophene and benzo[b]thiophene derivatives was developed via a sequence of propargyl–allenyl isomerization/cyclization/demethylation. As a result of the readily accessible starting materials, simple operation, and mild conditions, this reaction should have potential utility in organic synthesis.
2-(METHYLTHIO) BENZALDEHYDE Upstream and downstream
7022-45-9 Upstream product
92580-60-4
N'-p-Toluolsulfonyl-N-<2-methylmercapto-benzoyl>-hydrazin
33384-77-9
2-(methylthio)benzyl alcohol
89-98-5
2-chloro-benzaldehyde
5188-07-8
sodium thiomethoxide
77408-42-5
2-Methylthiobenzoesaeuremesitylester
77418-23-6
2-(Methylthio)thiobenzoesaeure-S-mesitylester
75087-02-4
<2-methylthio-α-oxo-phenylmethan>-diphenylphosphin
26190-68-1
1-chloromethyl-2-methylsulfanylbenzene
7022-45-9 Downstream Products
90922-21-7
2-Nitro-1-(2-methylmercapto-phenyl)-propen-(1)
35717-55-6
1-(2-Methylthiophenyl)-2-(4-nitrophenyl)ethanol
1025924-86-0
4-Methyl-2-(2-methylsulfanyl-phenyl)-5-pyridin-3-yl-imidazol-1-ol
145901-85-5
5-Ethyl-6-methyl-3-(2-methylsulfanyl-benzylamino)-1H-pyridin-2-one
3724-10-5
2-(methylthio)benzoic acid
103785-49-5
methyl 2-(2-methylthiophenylmethylene)acetoacetate
70401-49-9
o-(methylthio)benzaldehyde p-tosylhydrazone
134749-78-3
1-Methylsulfanyl-2-((E)-styryl)-benzene
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