Products
Diethyl(phenylacetyl)malonate
Another name：phenylacetyl-malonic acid diethyl ester;Phenylacetyl-malonsaeure-diaethylester;Phenylacetylmalonsaeurediethylester;
CasNo: 20320-59-6 Purity： ≥98% Molecular Structure： C15H18O5
Diethyl(phenylacetyl)malonate Basic Product Information
| Product Name | Diethyl(phenylacetyl)malonate | CAS | 20320-59-6 |
| Synonyms |
phenylacetyl-malonic acid diethyl ester; Phenylacetyl-malonsaeure-diaethylester; |
Molecular Formula | C15H18O5 |
| EINECS Number | 205-854-1 | Molecular Structure | |
| Appearance | Wine red oily liquid |
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| Purity | ≥98% | ||
| Supply Ability | 1T / Per Month | ||
Diethyl(phenylacetyl)malonate Appearance/Package/Shipping/Storage
Package
25kg/drum
Storage condition
Store in a cool, dry, and sealed place；
Diethyl(phenylacetyl)malonate Application
Organic synthesis intermediates, pharmaceutical intermediates;
Diethyl(phenylacetyl)malonate literature
Comprehensive study on excited state intramolecular proton transfer in 2-(benzo[d]thiazol-2-yl)-3-methoxynaphthalen-1-ol and 2-(benzo[d]thiazol-2-yl)naphthalene-1,3-diol: Effect of solvent, aggregation, viscosity and TDDFT study
Warde, Umesh,Nagaiyan, Sekar
, p. 33 - 43 (2017)
Three compounds DMT, MMT and DHT having dimehtoxy, mono-hydroxy and di-hydroxy groups respectively were prepared. Environmental interactions dependent photophysical properties especially excited state intramolecular proton transfer (ESIPT), solvatochromism, aggregation induced emission enhancement (AIEE) and viscosity dependent emission characteristics were studied. The effect of solvent polarity on ESIPT dynamics were studied using UV–vis and emission spectroscopy along with aggregation induced enhanced emission and viscosity effect. MMT and DHT showed unexpected and contrasting behavior in the solvents which are in good agreement with the density functional theory and time dependent density functional theory findings. Aggregation and viscosity study showed that cis-keto emission increased drastically in the aggregate state and highly viscous state due to restricted intramolecular rotation increasing the population of required cis enol rotamer (E). The study directs the potential applications of such molecules for advanced optoelectronics and viscosity based investigations.
The Interrupted Pummerer Reaction in a Sulfoxide-Catalyzed Oxidative Coupling of 2-Naphthols
He, Zhen,Pulis, Alexander P.,Procter, David J.
supporting information, p. 7813 - 7817 (2019/05/15)
A benzothiophene S-oxide catalyst, generated in situ by sulfur oxidation with H2O2, mediates the oxidative coupling of 2-naphthols. Key to the catalytic process is the capture and inversion of reactivity of a 2-naphthol partner, using an interrupted Pummerer reaction of an unusual benzothiophene S-oxide, followed by subsequent coupling with a second partner. The new catalytic manifold has been showcased in the synthesis of the bioactive natural products, (±)-nigerone and (±)-isonigerone. Although Pummerer reactions are used widely, their application in catalysis is rare, and our approach represents a new catalytic manifold for metal-free C?C bond formation.
INDOLIN-2-ONE DERIVATIVES AS PROTEIN KINASE INHIBITORS
-
, (2013/11/05)
A novel class of indoline-2-one derivatives are disclosed. These compounds are protein kinase inhibitors which are useful for treating hyperproliferative diseases such as cancer.
Novel Inhibitors of Hepatitis C Virus Replication
-
Page/Page column 52-53, (2009/10/21)
The embodiments provide compounds of the general Formula I, as well as compositions, including pharmaceutical compositions, comprising a subject compound. The embodiments further provide treatment methods, including methods of treating a hepatitis C virus infection and methods of treating liver fibrosis, the methods generally involving administering to an individual in need thereof an effective amount of a subject compound or composition.
Diethyl(phenylacetyl)malonate Upstream and downstream
20320-59-6 Upstream product
996-82-7
sodium diethylmalonate
103-80-0
phenylacetyl chloride
105-53-3
diethyl malonate
570-08-1
diethyl acetylmalonate
137786-67-5
ethyl 3-amino-2-ethoxycarbonyl-2-butenoate
2033-24-1
cycl-isopropylidene malonate
64-17-5
ethanol
74965-87-0
2,2-dimethyl-5-(2-phenylacetyl)-1,3-dioxane-4,6-dione
20320-59-6 Downstream Products
996-82-7
sodium diethylmalonate
103-80-0
phenylacetyl chloride
105-53-3
diethyl malonate
570-08-1
diethyl acetylmalonate
137786-67-5
ethyl 3-amino-2-ethoxycarbonyl-2-butenoate
2033-24-1
cycl-isopropylidene malonate
64-17-5
ethanol
74965-87-0
2,2-dimethyl-5-(2-phenylacetyl)-1,3-dioxane-4,6-dione
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