1560-95-8｜2-methyl tetradecane｜Kaimosi BioChem Tech Co., Ltd

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2-METHYLTETRADECANE Basic Product Information

Product Name	2-METHYLTETRADECANE	CAS	1560-95-8
Synonyms	isopentadecane	Molecular Formula	C15H32
EINECS Number	/	Molecular Structure
Appearance	Colorless liquid
Purity	≥97%
Supply Ability	500kg / Per Month

2-METHYLTETRADECANE Quality documents

2-METHYLTETRADECANE Appearance/Package/Shipping/Storage

Package

25kg/drum, 1kg/bottle, according to client's requirements

Storage condition

Store in cool, dry, and well ventilated place

2-METHYLTETRADECANE Application

Research and development

2-METHYLTETRADECANE literature

Process for hydrogenation of carboxylic acids and derivatives to hydrocarbons

Page/Page column 7-8, (2008/06/13)

A process for hydrogenating a carboxylic acid and/or derivative thereof having a carboxylate group represented by the general formula R¹COO^-, which process comprises feeding hydrogen and the carboxylic acid and/or derivative thereof to a reactor and maintaining conditions within the reactor such that hydrogen reacts with the carboxylic acid and/or derivative thereof to produce a product stream comprising carbon dioxide, carbon monoxide, methane and hydrocarbons represented by general formulae R¹H and R¹CH₃, characterised in that the molar ratio of R¹H : R¹CH₃ is above a pre-determined value and/or the mole ratio of the sum of carbon dioxide, carbon monoxide and methane to carboxylate groups is above a pre-determined value.

Geminal dialkylation, alkylative reduction and olefination of aliphatic aldehydes. Reaction of gem-bistriflates with higher order dialkylcyanocuprates

Garcia Martinez,Osio Barcina,Ruiz Diez,Subramanian

, p. 13231 - 13238 (2007/10/02)

gem-Dialkylation or alkylative reduction of α-unbranched aliphatic aldehydes 1 is advantageously achieved by reaction of the corresponding gem-bistriflates 2 with di-n-alkylcyanocuprates or di-sec- and di-tert-alkylcyanocuprates respectively. The reaction of α-branched gem-bistriflates 2 with dialkylcyanocuprates in the presence of boron trifluoride affords the olefins 6 in good yield.

Azo Anions in Synthesis: α-Amino Carbanion Equivalents from t-Butyldiphenylmethylhydrazones

Baldwin, Jack E.,Adlington, Robert M.,Newington, Ian M.

, p. 176 - 178 (2007/10/02)

α-Amino carbanion equivalents (=C(1-)NH2) and α-hydrazino anion equivalents (=C(1-)NHNH2) are readily accessible from the C-alkylation products of t-butyldiphenylmethylhydrazones; these azoalkanes can be efficiently transformed into amines, hydrazines, and also alkanes under mild reaction conditions.

AZO ANIONS IN SYNTHESIS. USE OF TRITYL- AND DIPHENYL-4-PYRIDYLMETHYLHYDRAZONES FOR REDUCTIVE C-C BOND FORMATION.

Baldwin, Jack E.,Adlington, Robert M.,Bottaro, Jeffrey C.,Kolhe, Jayant N.,Newington, Ian M.,Perry, Matthew W. D.

, p. 4235 - 4246 (2007/10/02)

The lithium salts of trityl- and diphenyl-4-pyridylmethyl-hydrazones of both aldehydes and ketones react with electrophiles (alkyl halides, aldehydes, ketones, crotonates) at low temperature to form C-trapped azo compounds; these intermediates decompose homolytically with loss of nitrogen below room temperature and can be diverted in a synthetically useful way to alkanes, alkenes, alcohols or saturated esters.

2-METHYLTETRADECANE Upstream and downstream

1560-95-8 Upstream product