Products
(S) -6-Methylnicotine
Another name：Pyridine;2-methyl-5-[(2S)-1-methyl-2-pyrrolidinyl]-;6-Methylnicotine;Nicotine;
CasNo: 13270-56-9 Purity： ≥99% Molecular Structure： C11H16N2
(S) -6-Methylnicotine Basic Product Information
| Product Name |
(S) -6-Methylnicotine |
CAS | 13270-56-9 |
| Synonyms |
Pyridine; 2-methyl-5-[(2S)-1-methyl-2-pyrrolidinyl]-; 6-Methylnicotine; |
Molecular Formula | |
| EINECS Number | 200-001-8 | Molecular Structure | |
| Appearance | Colorless to yellow liquid |
 |
|
| Purity | ≥99% | ||
| Supply Ability | 2T / Per Month | ||
(S) -6-Methylnicotine Appearance/Package/Shipping/Storage
Package
10L/drum or According to your requirements;
Storage condition
Low temperature, sealed, protected by nitrogen gas and kept away from light；
(S) -6-Methylnicotine Application
(S) -6-Methylnicotine literature
Organometallic Methylation of Nicotine and Nicotine N-Oxide. Rection Pathways and Racemization Mechanisms
Seeman, Jeffrey I.,Secor, Henry V.,Howe, Charles R.,Chavdarian, Charles G.,Morgan, Larry W.
, p. 4899 - 4904 (2007/10/02)
The reaction of nicotine with methyllithium leads to 2-methylnicotine as a major product in addition to the previously reported 4- and 6-methylnicotines.The reaction of nicotine N-oxide with methylmagnesium bromide furnishes both 2- and 6-methylnicotine.The product composition of these reactions is strongly dependent on the experimental conditions; the effects of solvent, temperature, and relative reagent concentration are presented.The methyllithium reactions lead to partially racemized methylnicotines, and the recovered nicotine is often nearly optically pure.Independently, (S)-(-)-6-methylnicotine was treated with methyllithium and was recovered with complete retention of optical activity.These results suggest that loss of optical purity in the formation of methylnicotines in these methyllithium reactions occurs during the reaction itself and is not due either to racemization of the starting material or to subsequent racemization of the initially formed product.
(S) -6-Methylnicotine Upstream and downstream
13270-56-9 Upstream product
917-54-4
methyllithium
54-11-5
nicotin
75-16-1
methylmagnesium bromide
2820-55-5
nicotine nitrogen oxide
13270-56-9 Downstream Products
917-54-4
methyllithium
54-11-5
nicotin
75-16-1
methylmagnesium bromide
2820-55-5
nicotine nitrogen oxide
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