methyl 2,4-dihydroxy-6-pentylbenzoate Basic Product Information

Product Name	methyl 2,4-dihydroxy-6-pentylbenzoate	CAS	58016-28-7
Synonyms	BEN570;Methyl olivetolate;methyl 2,6-dihydroxy-6-pentylbenzoate;methyl 6-n-pentyl-2,4-dihydroxybenzoate;methyl olivetocarboxylate;Benzoic acid,2,4-dihydroxy-6-pentyl-,methyl ester;2,4-Dihydroxy-6-pentyl-benzoesaeure-methylester;2,4-dihydroxy-6-pentyl-benzoic acid methyl ester;	Molecular Formula	C13H18O4
EINECS Number		Molecular Structure
Appearance	Light Yellow Powder
Purity	98.00%
Supply Ability

methyl 2,4-dihydroxy-6-pentylbenzoate Quality documents

methyl 2,4-dihydroxy-6-pentylbenzoate Appearance/Package/Shipping/Storage

package

storage condition

Store in cool & dry place,Keep away from strong light and heat

methyl 2,4-dihydroxy-6-pentylbenzoate Application

methyl 2,4-dihydroxy-6-pentylbenzoate literature

SYNTHESIS OF PHYTOCANNABINOIDS INCLUDING A DECARBOXYLATION STEP

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Page/Page column 16, (2019/03/05)

method for decarboxylating a carboxylated phytocannabinoid compound of Formula I to form a phytocannabinoid compound of Formula II: Formula I Formula II wherein: R1 is selected from the group consisting of: substituted or unsubstituted C₁-C₅ alkyl; R2 is selected from the group consisting of: OH or O, and R3 is selected from the group consisting of: a substituted or unsubstituted cyclohexene, a substituted or unsubstituted C₂-C₈ alkene, or a substituted or unsubstituted C₂-C₈ dialkene; or R2 is O, and R2 and R3 together form a ring structure in which R2 is an internal ring atom; wherein the method includes heating a reaction mixture comprising the carboxylated phytocannabinoid compound and a polar aprotic solvent in the presence of a LiCl for a time sufficient to decarboxylate at least a portion of the carboxylated phytocannabinoid compounds and form the phytocannabinoid compound.

SYNTHESIS OF PHYTOCANNABINOIDS INCLUDING A DEMETHYLATION STEP

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Page/Page column 16-17, (2019/03/05)

A method for demethylating a methylated phytocannabinoid compound of Formula I to form a phytocannabinoid compound of Formula II: Formula I Formula II wherein: R1 is selected from the group consisting of: substituted or unsubstituted C₁-C₅ alkyl; R2 is selected from the group consisting of: OH or O, and R3 is selected from the group consisting of: a substituted or unsubstituted cyclohexene, a substituted or unsubstituted C₂-C₈ alkene, or a substituted or unsubstituted C₂-C₈ dialkene; or R2 is O, and R2 and R3 together form a ring structure in which R2 is an internal ring atom; wherein the method includes: heating a reaction mixture comprising the methylated phytocannabinoid compounds and a polar aprotic solvent in the presence of a dissolved inorganic alkaline salt for a time sufficient to demethylate at least a portion of the methylated phytocannabinoid compounds and form the phytocannabinoid compound.

Chemistry of 1,3,5-Tris(trimethylsiloxy)-1-methoxyhexa-1,3,5-triene, a β-Tricarbonyl Trianion Equivalent

Chan, T. H.,Stoessel, D.

, p. 2423 - 2428 (2007/10/02)

The title compound has been synthesized and its chemistry studied.Condensation with orthoesters, acid chlorides, or imidazolides gave aromatic compounds in a 5C + 1C condensation.A formal synthesis of lasiodiplodin has been completed.

A BIOMIMETIC SYNTHESIS OF ¹Δ-TETRAHYDROCANNABIOL

Chan, T. H.,Chaly, T.

, p. 2935 - 2938 (2007/10/02)

Condensation of 1,3-bis(trimethylsiloxy)-1-methoxybutadiene with the acid chloride 12 gave methyl olivetolate (13).Condensation of 13 with (+)-p-mentha-2,8-dien-1-ol gave methyl ¹Δ-tetrahydrocannabiolate (14) in 55percent isolated yield.Alkaline hydrolysis of 14 gave ¹Δ-tetrahydrocannabinol (1, ¹Δ-THC).The synthesis is patterned after the biogenesis of 1.

methyl 2,4-dihydroxy-6-pentylbenzoate Upstream and downstream

58016-28-7 Upstream product

• 186581-53-3

  diazomethane 

• 491-72-5

  2,4-dihydroxyl-6-pentylbenzoic acid 

• 67-56-1

  methanol 

• 641-68-9

  anziaic acid 

• 60988-34-3

  1-(1-imidazolyl)-1-hexanone 

• 102342-54-1

  1,3,5-tris(trimethylsiloxy)-1-methoxyhexa-1,3,5-triene 

• 5830-30-8

  N,N-dimethylhexanamide 

• 29736-80-9

  3,5-dioxohexanoic acid methyl ester 

58016-28-7 Downstream Products

• 52189-68-1

  2-hydroxy-4-methoxy-6-pentylbenzoic acid 

• 94103-01-2

  methyl 4-benzyloxy-6-hydroxy-2-pentylbenzoate 

• 78135-63-4

  methyl 2-hydroxy-4-isopropyloxy-6-pentylbenzoate 

• 113487-78-8

  methyl 4-benzyloxy-2,5-dihydroxy-6-pentylbenzoate 

• 113487-85-7

  2-(5'-carboxy-2',4'-dihydro-6'-pentylphenoxy)-4-methoxy-6-propylbenzoic acid 

• 113487-80-2

  methyl 4-benzyloxy-3-(2'-hydroxy-4'-methoxy-6'-propylbenzoyloxy)-6-hydroxy-2-pentylbenzoate 

• 113500-97-3

  2-(2'-benzyloxy-5'-carboxy-4'-hydroxy-6'-pentylphenoxy)-4-methoxy-6-propylbenzoic acid 

• 113487-82-4

  2-(2'-benzyloxy-4'-hydroxy-5'-mrthoxycarbonyl-6'-pentylphenoxy)-4-methoxy-6-propylbenzoic acid 

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